jamtJournal of Advanced Materials and TechnologiesJournal of Advanced Materials and Technologies2782-21922782-2206ФГБОУ ВО «ТГТУ»10.17277/jamt.2023.02.pp.103-110jamt-30Research ArticleМатериалы для 3D-печати и аддитивного производстваMaterials for 3D printing and additive manufacturingВлияние малослойного графена на комплекс прочностных и теплофизических свойств полимерных композитов, полученных DLP-методом 3D-печатиInfluence of few-layer graphene on the complex of strength and thermophysical properties of polymer composites obtained by DLP by 3D printinghttps://orcid.org/0000-0001-6482-172XВозняковскийА. А.VozniakovskiiAleksei A.

Возняковский Алексей Александрович, кандидат химических наук, научный сотрудник, 

ул. Политехническая, 26, Санкт- Петербург,194021.

Aleksei A. Vozniakovskii, Cand. Sc. (Chem.), Researcher, 

26, Politekhnicheskaya St., St. Petersburg, 194021.

alexey_inform@mail.ruhttps://orcid.org/0000-0002-5685-9899КидаловС. В.KidalovSergey V.

Кидалов Сергей Викторович, кандидат физико-математических наук, ведущий научный сотрудник, 

ул. Политехническая, 26, Санкт- Петербург,194021.

Sergey V. Kidalov, Cand. Sc. (Phys. and Math.), Leading Researcher,

26, Politekhnicheskaya St., St. Petersburg, 194021.

kidalov@mail.ioffe.ruhttps://orcid.org/0000-0002-5979-3661ВозняковскийА. П.VoznyakovskiiAlexander P.

Возняковский Александр Петрович, доктор химических наук, заведующий сектором, 

ул. Гапсальская, 1, Санкт-Петербург, 198035

Alexander P. Voznyakovskii, D. Sc. (Chem.), Sector Manager, 

1, Gapsalskaya St., St. Petersburg, 198035.

voznap@mail.ruhttps://orcid.org/0000-0002-4414-6066ПодложнюкН. Д.PodlozhniukNikita D.

Подложнюк Никита Денисович, и.о. младшего научного сотрудника,

ул. Политехническая, 26, Санкт- Петербург,194021.

Nikita D. Podlozhniuk, Acting Junior Researcher, 

26, Politekhnicheskaya St., St. Petersburg, 194021.

nikigod.1@gmail.comhttps://orcid.org/0009-0007-5176-7892ТитоваС. И.TitovaSofia I.

Титова Софья Ивановна, лаборант, 

ул. Политехническая, 26, Санкт- Петербург,194021.

Sofya I. Titova, Laboratory Assistant, 

26, Politekhnicheskaya St., St. Petersburg, 194021.

rus.sofiatitova@gmail.comhttps://orcid.org/0000-0003-1454-7341ОвчинниковЕ. В.AuchynnikauEvgenii V.

Овчинников Евгений Витальевич, доктор технических наук, доцент, профессор кафедры машиностроения и технической эксплуатации автомобилей, 

ул. Элизы Ожешко, 22, Гродно, 230023.

 

Evgenii V. Auchynnikau, D. Sc. (Eng.), Associate Professor, Professor of the Department of Mechanical Engineering and Technical Operation of Vehicles, 

22, Eliza Ozheshko St., Grodno, 230023.

ovchin_1967@mail.ruФизико-технический институт им. А.Ф. Иоффе РАНРоссияIoffe InstituteRussian FederationНаучно-исследовательский институт синтетического каучука имени академика С. В. ЛебедеваРоссияS.V. Lebedev Research Institute of Synthetic RubberRussian FederationГродненский государственный университет имени Янки КупалыБеларусьYanka Kupala State University of GrodnoBelarus20231402202682103110Copyright © Возняковский А.А., Кидалов С.В., Возняковский А.П., Подложнюк Н.Д., Титова С.И., Овчинников Е.В., 20262026Возняковский А.А., Кидалов С.В., Возняковский А.П., Подложнюк Н.Д., Титова С.И., Овчинников Е.В.Vozniakovskii A.A., Kidalov S.V., Voznyakovskii A.P., Podlozhniuk N.D., Titova S.I., Auchynnikau E.V.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://jamt.elpub.ru/jour/article/view/30

Рассмотрена эффективность применения малослойного графена (число слоев не более 5), синтезированного по авторской методике в условиях самораспространяющегося высокотемпературного синтеза из целлюлозы в качестве модифицирующей добавки для повышения комплекса прочностных и теплофизических свойств изделий из фотополимерных смол, полученных методом DLP 3D-печати. Несмотря на высокие характеристики графеновых наноструктур, к которым относится и малослойный графен, данный класс материалов до сих пор не применяется в промышленности из-за невозможности синтеза больших объемов материала высокого качества и с приемлемой себестоимостью. Предложенный метод синтеза позволяет получать большие объемы малослойного графена, не содержащего в своей структуре дефекты Стоуна–Уэйлса. Установлено, что добавление малослойного графена позволяет добиться роста твердости по Бринеллю до 1,8 раз, прочности на изгиб до 1,5 раз и теплопроводности до 2,2 раз по сравнению с исходным полимером при использовании не более 2 масс. % малослойного графена. Дальнейшее увеличение концентрации малослойного графена не привело  к дальнейшему росту свойств конечного композита. Полученные данные свидетельствуют о высокой эффективности синтезированного малослойного графена в качестве модифицирующей добавки при создании изделий из фотополимерных смол методом DLP 3D-печати.

The digital light processing method (DIGITAL LIGHT PROCESSING or DLP) is one of the most affordable 3D printing methods, which allows you to obtain high-precision products, which, however, are inferior in their characteristics to products obtained by other 3D printing methods. Due to their high characteristics, graphene nanostructures can solve this problem by acting as effective modifying additives. However, despite all the promise of this approach, the introduction of graphene nanostructures into actual practice has not yet occurred due to their high cost due to the imperfection of the methods of their synthesis. The paper considers the effectiveness of using few-layer graphene synthesized according to the author's method under conditions of self-propagating high-temperature synthesis from cellulose as a modifying additive to improve the complex strength and thermophysical properties of products from photopolymer resins obtained by DLP 3D printing. It was found that adding few-layer graphene makes it possible to increase Brinell hardness up to 1.8 times, bending strength up to 1.5 times, and thermal conductivity up to 2.2 times compared to the original polymer when using no more than two wt. % few-layer graphene.The data obtained indicate the high efficiency of the synthesized few-layer graphene as a modifying additive in creating products from photopolymer resins using the DLP 3D printing method. 

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The authors declare that there are no conflicts of interest present.