jamtJournal of Advanced Materials and TechnologiesJournal of Advanced Materials and Technologies2782-21922782-2206ФГБОУ ВО «ТГТУ»10.17277/jamt-2025-10-01-008-018jamt-32Research ArticleНаноструктурированные наноматериалы и наноустройстваNanostructured, nanoscale materials and nanodevicesФормирование проводящих слоев на основе углеродных нанотрубок методом ЛенгмюраFormation of conductive layers based on carbon nanotubes by the Langmuir methodhttps://orcid.org/0009-0009-5404-6622ХассунО. А. Х.HassoonO. A. H.

Хассун Одай Али Хассун, инженер, Саратовский национальный исследовательский государственный университет имени Н. Г. Чернышевского (СГУ), Саратов; инженер, Министерство электроэнергетики, Багдад

ул. Астраханская, 83, Саратов, 410012

Багдад, 5815

Oday A. H. Hassoon, Engineer, Saratov State University (SSU; Engineer, Ministry of Electricity, Baghdad

83, Astrakhanskaya St., Saratov, 410012

Baghdad, P.O. Box 5815

uday_m82@yahoo.comhttps://orcid.org/0000-0002-0485-667XСалманО. Н.SalmanO. N.

Салман Одай Наеем, кандидат технических наук, доцент

Багдад, 19006

Odai N. Salman, Cand. Sc. (Eng.), Associate Professor

Baghdad, P.O. Box 19006

Odai.N.Salman@uotechnology.edu.iqhttps://orcid.org/0000-0001-9546-3646КаратышоваТ. Я.KaratyshovaT. Ya.

Каратышова Татьяна Яковлевна, инженер

ул. Астраханская, 83, Саратов, 410012

Tatiana Ya. Karatyshova, Engineer

Astrakhanskaya St., Saratov, 410012

tatochka338@gmail.comhttps://orcid.org/0000-0002-5665-464XАль-АлваниА. Ж. К.Al-AlwaniA. J. K.

Аль-Алвани Аммар Жабер Кадим, кандидат физико-математических наук, инженер, СГУ, Саратов; преподаватель, Аль-Фурат Аль-Авсат Технический университет, Технический институт Куфа, Ирак

ул. Астраханская, 83, Саратов, 410012

Куфа, Наджаф, Аль-Ашраф, 54001

Ammar J. K. Al-Alwani, Cand. Sc. (Phys. and Math.), Engineer, SSU, Saratov; Lecturer, Al-Furat Al-Awsat Technical University, Technical Institute Kufa, Iraq

83, Astrakhanskaya St., Saratov, 410012

Kufa, Najaf Al-Ashraf, P.O. Box 54001

ammarhamlet2013@yahoo.comhttps://orcid.org/0000-0002-1438-3060ГавриковМ. В.GavrikovM. V.

Гавриков Максим Владимирович, инженер

ул. Астраханская, 83, Саратов, 410012

Maxim V. Gavrikov, Engineer

83, Astrakhanskaya St., Saratov, 410012

maks.gavrikov.96@gmail.comhttps://orcid.org/0000-0001-5078-5422МиронюкВ. Н.MironyukV. N

Миронюк Владислав Николаевич, инженер

ул. Астраханская, 83, Саратов, 410012

Vladislav N. Mironyuk, Engineer

83, Astrakhanskaya St., Saratov, 410012

bestblogger@yandex.ruhttps://orcid.org/0000-0002-3813-5870ЗахаревичА. М.ZakharevichA. M.

Захаревич Андрей Михайлович, кандидат физико-математических наук, заведующий лабораторией

ул. Астраханская, 83, Саратов, 410012

Andrey M. Zakharevich, Cand. Sc. (Phys. ans Math.), Head of Laboratory

83, Astrakhanskaya St., Saratov, 410012

lab-15@mail.ruhttps://orcid.org/0000-0003-2914-7260ПожаровМ. В.PozharovM. V.

Пожаров Михаил Владимирович, кандидат химических наук, доцент

ул. Астраханская, 83, Саратов, 410012

Mikhail V. Pozharov, Cand. Sc. (Chem.), Associate Professor

83, Astrakhanskaya St., Saratov, 410012

pozharovmv@gmail.comhttps://orcid.org/0000-0002-8282-3638ГлуховскойЕ. Г.GlukhovskoyE. G.

Глуховской Евгений Геннадьевич, кандидат физико-математических наук, заведующий лабораторией

ул. Астраханская, 83, Саратов, 410012

Evgeny G. Glukhovskoy, Cand. Sc. (Phys. ans Math.), Head of Laboratory

83, Astrakhanskaya St., Saratov, 410012

glukhovskoy@gmail.comСаратовский национальный исследовательский государственный университет имени Н. Г. Чернышевского; Министерство электроэнергетикиИракSaratov State University; Ministry of ElectricityIraqТехнологический университетИракUniversity of Technology, Baghdad, P.O. Box 19006IraqСаратовский национальный исследовательский государственный университет имени Н. Г. ЧернышевскогоРоссияSaratov State UniversityRussian FederationСаратовский национальный исследовательский государственный университет имени Н. Г. Чернышевского; Аль-Фурат Аль-Авсат Технический университет, Технический институт КуфаИракSaratov State University; Al-Furat Al-Awsat Technical University, Technical Institute KufaIraq202516022026101818Copyright © Хассун О.Х., Салман О.Н., Каратышова Т.Я., Аль-Алвани А.К., Гавриков М.В., Миронюк В.Н., Захаревич А.М., Пожаров М.В., Глуховской Е.Г., 20262026Хассун О.Х., Салман О.Н., Каратышова Т.Я., Аль-Алвани А.К., Гавриков М.В., Миронюк В.Н., Захаревич А.М., Пожаров М.В., Глуховской Е.Г.Hassoon O.H., Salman O.N., Karatyshova T.Y., Al-Alwani A.K., Gavrikov M.V., Mironyuk V.N., Zakharevich A.M., Pozharov M.V., Glukhovskoy E.G.Данная работа распространяется под лицензией Creative Commons Attribution 4.0.This work is licensed under a Creative Commons Attribution 4.0 License.https://jamt.elpub.ru/jour/article/view/32

Методом изотерм сжатия и методом скачка потенциала исследованы ленгмюровские монослои, сформированные на основе индивидуальных растворов углеродных нанотрубок (УНТ) и их смесей с арахиновой кислотой (АК) в различных соотношениях. Эмпирически найдено оптимальное количество раствора УНТ (200 мкл) для формирования ленгмюровского слоя, который при переносе на твердую подложку имеет среднюю проводимость около 4.3⋅10–12 См/кв. Обнаружено также, что при нанесении второго и последующих слоев проводимость пленки увеличивается более чем на 6 порядков (до 5,08⋅10–6 См/кв). При исследовании смесей растворов углеродных нанотрубок (не имеющих амфифильных свойств) и арахиновой кислоты (типичного представителя поверхностно-активного вещества) найдено оптимальное соотношение объемов приготовленных растворов (УНТ : АК – 80 : 20), при котором возможен контроль степени сжатия слоя углеродных нанотрубок на поверхности жидкости. Показано, что введение в состав УНТ молекул АК позволяет дополнительно повысить проводимость пленки более чем на два порядка (до 1,18⋅10–3 См/кв), по сравнению с пленками индивидуальных УНТ. Исследованные пленки могут быть использованы в качестве платформы для создания различных устройств микро- и наноэлектроники, оптоэлектроники, фотовольтаики, а также гибкой электроники.

The compression isotherm and potential jump methods were used to study Langmuir monolayers formed from individual solutions of carbon nanotubes (CNTs) and their mixtures with arachidic acid (AA) in various ratios. The optimal amount of CNT solution (200 μL) for forming a Langmuir layer was empirically found. When transferred to a solid substrate, the layer has an average conductivity of about 4.3⋅10–12 S⋅sq–1. It was also found that when applying the second and subsequent layers, the film conductivity increases by more than 6 orders of magnitude (up to 5.08⋅10–6 S⋅sq–1).

In the study of mixtures of carbon nanotube solutions (without amphiphilic properties) and arachidic acid (a typical representative of a surfactant), an optimal ratio of the volumes of the prepared solutions was found (CNT : AA – 80 : 20), at which it is possible to control the degree of compression of the carbon nanotube layer on the surface of the aqueous subphase. It was shown that the introduction of AA molecules into the composition of CNTs allows an additional increase in the films conductivity by more than two orders of magnitude (up to 1.18⋅10–3 S⋅sq –1), compared to films of individual CNTs. The studied films can be used as a platform for the creation of various devices for micro- and nanoelectronics, optoelectronics, photovoltaics and flexible electronics.

метод Ленгмюра-Блоджеттуглеродные нанотрубкиленгмюровские монослоиарахиновая кислотаповерхностное натяжениепроводимость тонких пленокLangmuir-Blodgett methodcarbon nanotubesLangmuir monolayersarachidic acidsurface tensionthin films conductivityReferencesJia L, Zhang Y, Li J, You C, et al. Aligned singlewalled carbon nanotubes by Langmuir–Blodgett technique. Journal of Applied Physics. 2008;104(7):074318. DOI:10.1063/1.2996033Jia L, Zhang Y, Li J, You C, et al. Aligned singlewalled carbon nanotubes by Langmuir–Blodgett technique. Journal of Applied Physics. 2008;104(7):074318. DOI:10.1063/1.2996033Saito R, Dresselhaus G, Dresselhaus MS. Physical properties of carbon nanotubes. Tokyo:Imperial College Press; 1998. 272 p. DOI:10.1142/p080Saito R, Dresselhaus G, Dresselhaus MS. Physical properties of carbon nanotubes. Tokyo:Imperial College Press; 1998. 272 p. DOI:10.1142/p080Sun X, Li R, Stansfield B, Dodelet JP, et al. 3D carbon nanotube network based on a hierarchical structure grown on carbon paper backing. Chemical Physics Letters. 2004;394(4-6):266-270. DOI:10.1016/j.cplett.2004.07.014Sun X, Li R, Stansfield B, Dodelet JP, et al. 3D carbon nanotube network based on a hierarchical structure grown on carbon paper backing. Chemical Physics Letters. 2004;394(4-6):266-270. DOI:10.1016/j.cplett.2004.07.014Lu R, Christianson C, Weintrub B, Wu JZ. High photoresponse in hybrid graphene–carbon nanotube infrared detectors. ACS Applied Materials & Interfaces. 2013;5(22):11703-11707. DOI:10.1021/am4033313Lu R, Christianson C, Weintrub B, Wu JZ. High photoresponse in hybrid graphene–carbon nanotube infrared detectors. ACS Applied Materials & Interfaces. 2013;5(22):11703-11707. DOI:10.1021/am4033313Lu R, Christianson C, Kirkeminde A, Ren S, et al. Extraordinary photocurrent harvesting at type-II heterojunction interfaces: toward high detectivity carbon nanotube infrared detectors. Nano Letters. 2012;12(12): 6244-6249. DOI:10.1021/nl303302pLu R, Christianson C, Kirkeminde A, Ren S, et al. Extraordinary photocurrent harvesting at type-II heterojunction interfaces: toward high detectivity carbon nanotube infrared detectors. Nano Letters. 2012;12(12): 6244-6249. DOI:10.1021/nl303302pItkis ME, Borondics F, Yu A, Haddon RC. Bolometric infrared photoresponse of suspended singlewalled carbon nanotube films. Science. 2006;312(5772): 413-416. DOI:10.1126/science.1125695Itkis ME, Borondics F, Yu A, Haddon RC. Bolometric infrared photoresponse of suspended singlewalled carbon nanotube films. Science. 2006;312(5772): 413-416. DOI:10.1126/science.1125695Ali A, Rahimian Koloor SS, Alshehri AH, Arockiarajan A. Carbon nanotube characteristics and enhancement effects on the mechanical features of polymer-based materials and structures – a review. Journal of Materials Research and Technology. 2023;24:6495-6521. DOI:10.1016/j.jmrt.2023.04.072Ali A, Rahimian Koloor SS, Alshehri AH, Arockiarajan A. Carbon nanotube characteristics and enhancement effects on the mechanical features of polymer-based materials and structures – a review. Journal of Materials Research and Technology. 2023;24:6495-6521. DOI:10.1016/j.jmrt.2023.04.072Wu J, Lan Z, Lin J, Huang M, et al. Counter electrodes in dye-sensitized solar cells. Chemical Society Reviews. 2017;46(19):5975-6023. DOI:10.1039/C6CS00752JWu J, Lan Z, Lin J, Huang M, et al. Counter electrodes in dye-sensitized solar cells. Chemical Society Reviews. 2017;46(19):5975-6023. DOI:10.1039/C6CS00752JIEEE International roadmap for devices and systems: 2017 edition. Available from: https://irds.ieee.org/editions/2017 [Accessed: 3 December 2024].IEEE International roadmap for devices and systems: 2017 edition. Available from: https://irds.ieee.org/editions/2017 [Accessed: 3 December 2024].Venkataraman A, Amadi EV, Chen Y, Papadopoulos C. Carbon nanotube assembly and integration for applications. Nanoscale Research Letters. 2019;14(1):220. DOI:10.1186/s11671-019-3046-3Venkataraman A, Amadi EV, Chen Y, Papadopoulos C. Carbon nanotube assembly and integration for applications. Nanoscale Research Letters. 2019;14(1):220. DOI:10.1186/s11671-019-3046-3Moriarty P. Nanostructured materials. Reports on Progress in Physics. 2001;64(3):297-381. DOI:10.1088/0034-4885/64/3/201Moriarty P. Nanostructured materials. Reports on Progress in Physics. 2001;64(3):297-381. DOI:10.1088/0034-4885/64/3/201Huang KC, Wang YC, Dong RX, Tsai WC, et al. A high performance dye-sensitized solar cell with a novel nanocomposite film of PTNP/MWCNT on the counter electrode. Journal of Materials Chemistry. 2010;20(20): 4067. DOI:10.1039/b925245bHuang KC, Wang YC, Dong RX, Tsai WC, et al. A high performance dye-sensitized solar cell with a novel nanocomposite film of PTNP/MWCNT on the counter electrode. Journal of Materials Chemistry. 2010;20(20): 4067. DOI:10.1039/b925245bOliveira ON, Caseli L, Ariga K. The past and the future of Langmuir and Langmuir–Blodgett films. Chemical Reviews. 2022;122(6):6459-6513. DOI:10.1021/acs.chemrev.1c00754Oliveira ON, Caseli L, Ariga K. The past and the future of Langmuir and Langmuir–Blodgett films. Chemical Reviews. 2022;122(6):6459-6513. DOI:10.1021/acs.chemrev.1c00754Adamson AW, Gast AP. Physical chemistry of surfaces. New York: Wiley; 1997. 784 p.Adamson AW, Gast AP. Physical chemistry of surfaces. New York: Wiley; 1997. 784 p.Petty MC. Langmuir-Blodgett films: An introduction. New York: Cambridge University Press; 1996. 234 p.Petty MC. Langmuir-Blodgett films: An introduction. New York: Cambridge University Press; 1996. 234 p.Gorbachev IA, Gluhovskoy EG. The studying of components ratio influence in mixed monolayers of quantum dots and arachidic acid on the films morphology based on them. Izvestiya Saratovskogo universiteta. Novaya seriya. Seriya: khimiya. biologiya. ekologiya. 2018;18(3):299-305. DOI:10.18500/1816-9775-2018-18-3-299-305 (In Russ.)Gorbachev IA, Gluhovskoy EG. The studying of components ratio influence in mixed monolayers of quantum dots and arachidic acid on the films morphology based on them. Izvestiya Saratovskogo universiteta. Novaya seriya. Seriya: khimiya. biologiya. ekologiya. 2018;18(3):299-305. DOI:10.18500/1816-9775-2018-18-3-299-305 (In Russ.)Gorbachev I, Smirnov A, Ivanov G, Avramov I, et al. Langmuir-Blodgett films of arachidic and stearic acids as sensitive coatings for chloroform hf saw sensors. Sensors. 2022;23(1):100. DOI:10.3390/s23010100Gorbachev I, Smirnov A, Ivanov G, Avramov I, et al. Langmuir-Blodgett films of arachidic and stearic acids as sensitive coatings for chloroform hf saw sensors. Sensors. 2022;23(1):100. DOI:10.3390/s23010100Hadjichristov GB, Marinov YG, Vlakhov TE, Scaramuzza N. Phospholipid Langmuir-Blodgett nano-thin monolayers: electrical response to cadmium ions and harmful volatile organic compounds. In: Advances in Biomembranes and Lipid Self-Assembly. Elsevier; 2021. p. 129-172. DOI:10.1016/bs.abl.2021.11.005Hadjichristov GB, Marinov YG, Vlakhov TE, Scaramuzza N. Phospholipid Langmuir-Blodgett nano-thin monolayers: electrical response to cadmium ions and harmful volatile organic compounds. In: Advances in Biomembranes and Lipid Self-Assembly. Elsevier; 2021. p. 129-172. DOI:10.1016/bs.abl.2021.11.005Zubova KV, Kuznetsova VA, Al-Alwani AJK, Glinskaya EV, et al. Characteristics of Langmuir monolayers of phospholipids isolated from the cell membranes of the E. coli K-12 test culture. Aktual′nyye voprosy biologicheskoy fiziki i khimii. 2021;6(2):285-288. (In Russ.)Zubova KV, Kuznetsova VA, Al-Alwani AJK, Glinskaya EV, et al. Characteristics of Langmuir monolayers of phospholipids isolated from the cell membranes of the E. coli K-12 test culture. Aktual′nyye voprosy biologicheskoy fiziki i khimii. 2021;6(2):285-288. (In Russ.)Klimov BN, Glukhovskoy EG. Visualization of the structure of Langmuir-Blodgett films in liquid crystal cells. Zhurnal tekhnicheskoy fiziki = Technical Physics. 2002;72(12):94-97. (In Russ.)Klimov BN, Glukhovskoy EG. Visualization of the structure of Langmuir-Blodgett films in liquid crystal cells. Zhurnal tekhnicheskoy fiziki = Technical Physics. 2002;72(12):94-97. (In Russ.)Al-Alwani AJK, Chumakov AS, Kolesnikova AS, Pozharov MV, et al. Investigation of the properties of semiconductor quantum dots on dielectric Langmuir monolayers. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Tekhnika i tekhnologii. 2019;9(1)(30):56-67. (In Russ.)Al-Alwani AJK, Chumakov AS, Kolesnikova AS, Pozharov MV, et al. Investigation of the properties of semiconductor quantum dots on dielectric Langmuir monolayers. Izvestiya Yugo-Zapadnogo gosudarstvennogo universiteta. Seriya: Tekhnika i tekhnologii. 2019;9(1)(30):56-67. (In Russ.)Mironyuk VN, Al-Alwani AJK, Karatyshova TYa, Smirnova AI, et al. Influence of subphase temperature on Langmuir layers and thin films of A3B-type porphyrine derivative. Surfaces and Interfaces. 2024;52:104880. DOI:10.1016/j.surfin.2024.104880Mironyuk VN, Al-Alwani AJK, Karatyshova TYa, Smirnova AI, et al. Influence of subphase temperature on Langmuir layers and thin films of A3B-type porphyrine derivative. Surfaces and Interfaces. 2024;52:104880. DOI:10.1016/j.surfin.2024.104880Al-Hassani AJR, Al-Alwani AJ, Mironyuk VN, Pozharov MV. Miscibility of porphyrin/liquid crystal floating monolayers at the air–water interface. Phase Transitions. 2024;97(3):192-200. DOI:10.1080/01411594.2023.2301465Al-Hassani AJR, Al-Alwani AJ, Mironyuk VN, Pozharov MV. Miscibility of porphyrin/liquid crystal floating monolayers at the air–water interface. Phase Transitions. 2024;97(3):192-200. DOI:10.1080/01411594.2023.2301465Wu Y, Liu Z, Zhou S, Wang F, et al. Langmuir-Blodgett assembly of carboxylic multiwalled carbon nanotubes-nafion for amperometric sensing of codeine. Journal of The Electrochemical Society. 2019;166(13): H592-H597. DOI:10.1149/2.0371913jesWu Y, Liu Z, Zhou S, Wang F, et al. Langmuir-Blodgett assembly of carboxylic multiwalled carbon nanotubes-nafion for amperometric sensing of codeine. Journal of The Electrochemical Society. 2019;166(13): H592-H597. DOI:10.1149/2.0371913jesMatsui J, Iko M, Inokuma N, Orikasa H, et al. Fabrication of carbon nanotube Langmuir-Blodgett film by polyion complex method. In: Materials Research Society Symposium Proceedings. 2006;963:208-211. DOI:10.1557/PROC-0963-Q05-35Matsui J, Iko M, Inokuma N, Orikasa H, et al. Fabrication of carbon nanotube Langmuir-Blodgett film by polyion complex method. In: Materials Research Society Symposium Proceedings. 2006;963:208-211. DOI:10.1557/PROC-0963-Q05-35Hrushevsky VV, Krylova HV, Lipnevich IV, Shulitsky BG, et al. Clusterization and spontaneous polarization in thin Langmuir – Blodgett films with modified multi-walled carbon nanotubes. Proceedings of the “Foundations & Advances in Nonlinear Science” Conference-School. Minsk: Belarusian State University; 2009. p. 50-60.Hrushevsky VV, Krylova HV, Lipnevich IV, Shulitsky BG, et al. Clusterization and spontaneous polarization in thin Langmuir – Blodgett films with modified multi-walled carbon nanotubes. Proceedings of the “Foundations & Advances in Nonlinear Science” Conference-School. Minsk: Belarusian State University; 2009. p. 50-60.Lo CL, Lee YL, Hsu WP. Behavior of mixed multi-walled carbon nanotube/p3ht monolayer at the air/water interface. Synthetic Metals. 2010;160(19-20): 2219-2223. DOI:10.1016/j.synthmet.2010.08.014Lo CL, Lee YL, Hsu WP. Behavior of mixed multi-walled carbon nanotube/p3ht monolayer at the air/water interface. Synthetic Metals. 2010;160(19-20): 2219-2223. DOI:10.1016/j.synthmet.2010.08.014Multi walled carbon nanotubes for research and commercial applications. Available from: https://www. ctimaterials.com/product-category/multi-walled-carbonnanotubes/ [Accessed: 3 December 2024].Multi walled carbon nanotubes for research and commercial applications. Available from: https://www. ctimaterials.com/product-category/multi-walled-carbonnanotubes/ [Accessed: 3 December 2024].Tajuelo J, Guzmán E, Ortega F, Rubio RG, et al. Phase diagram of fatty acid Langmuir monolayers from rheological measurements. Langmuir. 2017;33(17):4280-4290. DOI:10.1021/acs.Langmuir.7b00613Tajuelo J, Guzmán E, Ortega F, Rubio RG, et al. Phase diagram of fatty acid Langmuir monolayers from rheological measurements. Langmuir. 2017;33(17):4280-4290. DOI:10.1021/acs.Langmuir.7b00613Lvov YuM, Feigin LA. Langmuir films production, structure, some applications. Kristallografiya = Soviet Physics. Crystallography. 1987;32(3):800-815. (In Russ.)Lvov YuM, Feigin LA. Langmuir films production, structure, some applications. Kristallografiya = Soviet Physics. Crystallography. 1987;32(3):800-815. (In Russ.)Moehwald H, Brezesinski G. From Langmuir monolayers to multilayer films. Langmuir. 2016;32(41): 10445-10458. DOI:10.1021/acs.Langmuir.6b02518Moehwald H, Brezesinski G. From Langmuir monolayers to multilayer films. Langmuir. 2016;32(41): 10445-10458. DOI:10.1021/acs.Langmuir.6b02518Ngoma MM, Mathaba M, Moothi K. Effect of carbon nanotubes loading and pressure on the performance of a polyethersulfone (PES)/carbon nanotubes (CNT) membrane. Scientific Reports. 2021;11(1):23805. DOI:10.1038/s41598-021-03042-zNgoma MM, Mathaba M, Moothi K. Effect of carbon nanotubes loading and pressure on the performance of a polyethersulfone (PES)/carbon nanotubes (CNT) membrane. Scientific Reports. 2021;11(1):23805. DOI:10.1038/s41598-021-03042-z

The authors declare that there are no conflicts of interest present.