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<article article-type="research-article" dtd-version="1.3" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xml:lang="ru"><front><journal-meta><journal-id journal-id-type="publisher-id">jamt</journal-id><journal-title-group><journal-title xml:lang="ru">Journal of Advanced Materials and Technologies</journal-title><trans-title-group xml:lang="en"><trans-title>Journal of Advanced Materials and Technologies</trans-title></trans-title-group></journal-title-group><issn pub-type="ppub">2782-2192</issn><issn pub-type="epub">2782-2206</issn><publisher><publisher-name>ФГБОУ ВО «ТГТУ»</publisher-name></publisher></journal-meta><article-meta><article-id pub-id-type="doi">10.17277/jamt.2024.04.pp.312-325</article-id><article-id custom-type="elpub" pub-id-type="custom">jamt-44</article-id><article-categories><subj-group subj-group-type="heading"><subject>Research Article</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="ru"><subject>Современные конструкционные материалы, материалы для экстремальных условий</subject></subj-group><subj-group subj-group-type="section-heading" xml:lang="en"><subject>Advanced structural materials, materials for extreme conditions</subject></subj-group></article-categories><title-group><article-title>Десорбция газов из материалов катодов в электровакуумных приборах в процессе производства</article-title><trans-title-group xml:lang="en"><trans-title>Desorption of gases from cathode materials in electrovacuum devices during the production process</trans-title></trans-title-group></title-group><contrib-group><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0009-0009-4173-9227</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Паращук</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Parashchuk</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Паращук Анастасия Владиславовна, аспирант</p><p>Институтский пер., 9, Долгопрудный, 141701</p></bio><bio xml:lang="en"><p>Anastasia V. Parashchuk, Postgraduate Student</p><p>9, Institutsky Ln., Dolgoprudny, 141701</p><p> </p></bio><email xlink:type="simple">parashchuk.av@mipt.ru</email><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><contrib-id contrib-id-type="orcid">https://orcid.org/0000-0003-2750-4797</contrib-id><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Шешин</surname><given-names>Е. П.</given-names></name><name name-style="western" xml:lang="en"><surname>Shehin</surname><given-names>E. P.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Шешин Евгений Павлович, доктор физико-математических наук, профессор, заместительзаведующего кафедрой</p><p>Институтский пер., 9, Долгопрудный, 141701</p></bio><bio xml:lang="en"><p>Evgeniy P. Shehin, D. Sc. (Phys. and Math.), Professor,Deputy Head of the Department</p><p>9, Institutsky Ln., Dolgoprudny, 141701</p></bio><xref ref-type="aff" rid="aff-1"/></contrib><contrib contrib-type="author" corresp="yes"><name-alternatives><name name-style="eastern" xml:lang="ru"><surname>Шуманов</surname><given-names>А. В.</given-names></name><name name-style="western" xml:lang="en"><surname>Shumanov</surname><given-names>A. V.</given-names></name></name-alternatives><bio xml:lang="ru"><p>Шуманов Алексей Владимирович, начальникотделения катодно-вакуумных систем</p><p>ул. Нижняя Сыромятническая, 11, Москва, 105120</p></bio><bio xml:lang="en"><p>Aleksey V. Shumanov, Head of the Department ofCathode-vacuum systems</p><p>11, Nizhnyaya Syromyatnicheskaya St., Moscow, 105120</p></bio><xref ref-type="aff" rid="aff-2"/></contrib></contrib-group><aff-alternatives id="aff-1"><aff xml:lang="ru"><institution>Московский физико-технический институт (национальный исследовательский университет)</institution><country>Россия</country></aff><aff xml:lang="en"><institution>Moscow Institute of Physics and Technology (MIPT)</institution><country>Russian Federation</country></aff></aff-alternatives><aff-alternatives id="aff-2"><aff xml:lang="ru"><institution>АО «Плутон»</institution><country>Россия</country></aff><aff xml:lang="en"><institution>JSC "Pluton"</institution><country>Russian Federation</country></aff></aff-alternatives><pub-date pub-type="collection"><year>2024</year></pub-date><pub-date pub-type="epub"><day>13</day><month>02</month><year>2026</year></pub-date><volume>9</volume><issue>4</issue><fpage>312</fpage><lpage>325</lpage><permissions><copyright-statement>Copyright &amp;#x00A9; Паращук А.В., Шешин Е.П., Шуманов А.В., 2026</copyright-statement><copyright-year>2026</copyright-year><copyright-holder xml:lang="ru">Паращук А.В., Шешин Е.П., Шуманов А.В.</copyright-holder><copyright-holder xml:lang="en">Parashchuk A.V., Shehin E.P., Shumanov A.V.</copyright-holder><license xml:lang="ru" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>Данная работа распространяется под лицензией Creative Commons Attribution 4.0.</license-p></license><license xml:lang="en" license-type="creative-commons-attribution" xlink:href="https://creativecommons.org/licenses/by/4.0/" xlink:type="simple"><license-p>This work is licensed under a Creative Commons Attribution 4.0 License.</license-p></license></permissions><self-uri xlink:href="https://jamt.elpub.ru/jour/article/view/44">https://jamt.elpub.ru/jour/article/view/44</self-uri><abstract><p>Десорбция газов из материалов катодов в электровакуумных приборах (ЭВП) является одной из ключевых проблем в процессе производства, оказывающей существенное влияние на производительность и долговечность таких устройств, как магнетроны, рентгеновские трубки и вакуумные усилители. К примеру, очищение поверхностей деталей ЭВП в процессе производства неизбежно влечет за собой их реакции с компонентами воздуха после извлечения из зоны обработки, а процесс обезгаживающего нагрева во время откачки нередко способствует дополнительному усложнению структуры и химического состава поверхностного слоя, поскольку примеси, диффундирующие к поверхности, могут вызвать появление новых веществ. Поэтому даже при выборе материалов катодов, деталей внутренней арматуры ЭВП руководствуются способностью материала быстро удалять газы, сохранять прочность при высоких температурах и обладать высокой химической устойчивостью. Приведен подробный анализ современных методов ускорения десорбции, механизмов этого процесса и их расчетных основ, включая известные физические законы и модели адсорбции и десорбции. Оценены перспективные подходы к улучшению качества катодов на разных этапах их производства, с акцентом на использование новых материалов и технологий. Проанализированы расчеты, подтверждающие эффективность предложенных решений, а также влияние различных факторов на минимизацию влияния процессов десорбции и повышение долговечности катодов в ЭВП.</p></abstract><trans-abstract xml:lang="en"><p>Desorption of gases from cathode materials in electrovacuum devices (EVDs) is one of the key problems in the production process, which has a significant impact on the performance and durability of devices such as magnetrons, X-ray tubes and vacuum amplifiers. For example, cleaning the surfaces of EVD parts during production inevitably entails their reactions with air components after extraction from the processing zone, and the process of degassing heating during pumping often contributes to an additional complication of the structure and chemical composition of the surface layer, since impurities diffusing to the surface can cause the appearance of new substances. Therefore, even when choosing cathode materials or parts of internal fittings, EVDs are guided by the ability of the material to quickly remove gases, maintain strength at high temperatures and have high chemical resistance. The present paper is a detailed analysis of modern methods of desorption acceleration, the mechanisms of this process and their computational basis, including known physical laws and models of adsorption and desorption. Promising approaches to improving the quality of cathodes at different stages of their production, with an emphasis on the use of new materials and technologies, are evaluated. Calculations confirming the effectiveness of the proposed solutions are analyzed, as well as the influence of various factors on minimizing the impact of desorption processes and increasing the durability of cathodes in EVDs.</p></trans-abstract><kwd-group xml:lang="ru"><kwd>десорбция</kwd><kwd>материалы катодов</kwd><kwd>термодесорбция</kwd><kwd>вакуумные технологии</kwd><kwd>газовыделение</kwd><kwd>электровакуумные приборы</kwd><kwd>откачка</kwd><kwd>эмиссионные свойства</kwd><kwd>ионная очистка</kwd><kwd>кинетика десорбции</kwd></kwd-group><kwd-group xml:lang="en"><kwd>desorption</kwd><kwd>cathode materials</kwd><kwd>thermal desorption</kwd><kwd>vacuum technologies</kwd><kwd>gas release</kwd><kwd>electro-vacuum devices</kwd><kwd>pumping</kwd><kwd>emission properties</kwd><kwd>ion purification</kwd><kwd>desorption kinetics</kwd></kwd-group></article-meta></front><back><ref-list><title>References</title><ref id="cit1"><label>1</label><citation-alternatives><mixed-citation xml:lang="ru">Influence of the vacuum state on the field emission properties of the cathode-heating unit of magnetrons with instant readiness. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Moscow: Nanoindustry; 2021. p. 278-282. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Influence of the vacuum state on the field emission properties of the cathode-heating unit of magnetrons with instant readiness. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Moscow: Nanoindustry; 2021. p. 278-282. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit2"><label>2</label><citation-alternatives><mixed-citation xml:lang="ru">Li IP, Kapustin VI, Ledentsova NE, Shumanov AV. Design features of three-module cathode heating units of magnetrons with instant readiness. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Moscow: Nanoindustry; 2021. p. 283-288. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Li IP, Kapustin VI, Ledentsova NE, Shumanov AV. Design features of three-module cathode heating units of magnetrons with instant readiness. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Moscow: Nanoindustry; 2021. p. 283-288. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit3"><label>3</label><citation-alternatives><mixed-citation xml:lang="ru">Khanbekov IF, Mikhailov VP. Research of the ultrasonic activation processes of diffusion and desorption in electrovacuum devices. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Moscow: Nanoindustry; 2021. p. 306-310. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Khanbekov IF, Mikhailov VP. Research of the ultrasonic activation processes of diffusion and desorption in electrovacuum devices. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Moscow: Nanoindustry; 2021. p. 306-310. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit4"><label>4</label><citation-alternatives><mixed-citation xml:lang="ru">Gaertner G. History of vacuum electronics and vacuum electron sources and future development trends. Modern Developments in Vacuum Electron Sources. 135. Cham: Springer; 2020. p. 1-31.</mixed-citation><mixed-citation xml:lang="en">Gaertner G. History of vacuum electronics and vacuum electron sources and future development trends. Modern Developments in Vacuum Electron Sources. 135. Cham: Springer; 2020. p. 1-31.</mixed-citation></citation-alternatives></ref><ref id="cit5"><label>5</label><citation-alternatives><mixed-citation xml:lang="ru">Ogura S, Fukutani K. Thermal desorption spectroscopy. Compendium of Surface and Interface Analysis. Singapore: Springer; 2018. p. 719-724.</mixed-citation><mixed-citation xml:lang="en">Ogura S, Fukutani K. Thermal desorption spectroscopy. Compendium of Surface and Interface Analysis. Singapore: Springer; 2018. p. 719-724.</mixed-citation></citation-alternatives></ref><ref id="cit6"><label>6</label><citation-alternatives><mixed-citation xml:lang="ru">Umirzakov BE, Sadikzhanov Zh, Tashmukhamedova DA, Abduvaitov A, Rabbimov EA. The effect of adsorption of Ba atoms on the composition, emission and optical properties of CdS single crystals. Pis′ma v zhurnal tekhnicheskoy fiziki = Letters to the Journal of Technical Physics. 2021;47(12):3. DOI:10.21883/PJTF.2021.12.51057.18632 (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Umirzakov BE, Sadikzhanov Zh, Tashmukhamedova DA, Abduvaitov A, Rabbimov EA. The effect of adsorption of Ba atoms on the composition, emission and optical properties of CdS single crystals. Pis′ma v zhurnal tekhnicheskoy fiziki = Letters to the Journal of Technical Physics. 2021;47(12):3. DOI:10.21883/PJTF.2021.12.51057.18632 (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit7"><label>7</label><citation-alternatives><mixed-citation xml:lang="ru">Ubbelohde ARJP, Alfred CE. The kinetics of adsorption processes. Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character. 1931;134(824):512-523. DOI:10.1098/rspa.1931.0211</mixed-citation><mixed-citation xml:lang="en">Ubbelohde ARJP, Alfred CE. The kinetics of adsorption processes. Proceedings of the Royal Society of London. Series A, Containing Papers of a Mathematical and Physical Character. 1931;134(824):512-523. DOI:10.1098/rspa.1931.0211</mixed-citation></citation-alternatives></ref><ref id="cit8"><label>8</label><citation-alternatives><mixed-citation xml:lang="ru">Langmuir I. The effect of space charge and residual gases on thermionic currents in high vacuum. Physical Review. 1913;2(6):450-486. DOI:10.1103/PhysRev.2.450</mixed-citation><mixed-citation xml:lang="en">Langmuir I. The effect of space charge and residual gases on thermionic currents in high vacuum. Physical Review. 1913;2(6):450-486. DOI:10.1103/PhysRev.2.450</mixed-citation></citation-alternatives></ref><ref id="cit9"><label>9</label><citation-alternatives><mixed-citation xml:lang="ru">Nottingham WB. Thermionic emission. ElectronEmission Gas Discharges I / Elektronen-Emission Gasentladungen I. Berlin: Springer; 1956. V. 4(12). p. 1-175.</mixed-citation><mixed-citation xml:lang="en">Nottingham WB. Thermionic emission. ElectronEmission Gas Discharges I / Elektronen-Emission Gasentladungen I. Berlin: Springer; 1956. V. 4(12). p. 1-175.</mixed-citation></citation-alternatives></ref><ref id="cit10"><label>10</label><citation-alternatives><mixed-citation xml:lang="ru">Wei FG, Hara T, Tsuzaki K. Precise determination of the activation energy for desorption of hydrogen in two Ti-added steels by a single thermaldesorption spectrum. Metallurgical and Materials Transactions B. 2004;35(3):587-597. DOI:10.1007/s11663-004-0057-x</mixed-citation><mixed-citation xml:lang="en">Wei FG, Hara T, Tsuzaki K. Precise determination of the activation energy for desorption of hydrogen in two Ti-added steels by a single thermaldesorption spectrum. Metallurgical and Materials Transactions B. 2004;35(3):587-597. DOI:10.1007/s11663-004-0057-x</mixed-citation></citation-alternatives></ref><ref id="cit11"><label>11</label><citation-alternatives><mixed-citation xml:lang="ru">Gao J-Y, Yang Y-F, Zhang X-K, Li S-L, et al. A review on recent progress of thermionic cathode. Tungsten. 2020;2(3):289-300. DOI:10.1007/s42864-020-00059-1</mixed-citation><mixed-citation xml:lang="en">Gao J-Y, Yang Y-F, Zhang X-K, Li S-L, et al. A review on recent progress of thermionic cathode. Tungsten. 2020;2(3):289-300. DOI:10.1007/s42864-020-00059-1</mixed-citation></citation-alternatives></ref><ref id="cit12"><label>12</label><citation-alternatives><mixed-citation xml:lang="ru">Ono K, Meshii M. Hydrogen detrapping from grain boundaries and dislocations in high purity iron. Acta Metallurgica et Materialia. 1992;40(6):1357-1364. DOI:10.1016/0956-7151(92)90436-I</mixed-citation><mixed-citation xml:lang="en">Ono K, Meshii M. Hydrogen detrapping from grain boundaries and dislocations in high purity iron. Acta Metallurgica et Materialia. 1992;40(6):1357-1364. DOI:10.1016/0956-7151(92)90436-I</mixed-citation></citation-alternatives></ref><ref id="cit13"><label>13</label><citation-alternatives><mixed-citation xml:lang="ru">Sveshnikov VK, Bazarkin AF. Physical model and computer calculation of the diffusion coefficient of sodium into the oxide coating of the cathode. Fundamental′nye Issledovaniya = Fundamental research. 2014;(5-5):990-993. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Sveshnikov VK, Bazarkin AF. Physical model and computer calculation of the diffusion coefficient of sodium into the oxide coating of the cathode. Fundamental′nye Issledovaniya = Fundamental research. 2014;(5-5):990-993. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit14"><label>14</label><citation-alternatives><mixed-citation xml:lang="ru">Seif MN, Balk TJ, Beck MJ. Temperature effects on desorption behavior and characteristic Wulff shapes of scandate cathodes. 2020 IEEE 21st International Conference on Vacuum Electronics (IVEC) 20-23 April 2020. Monterey: IEEE; 2020. p. 83-84. DOI:10.1109/ IVEC45766.2020.9520596</mixed-citation><mixed-citation xml:lang="en">Seif MN, Balk TJ, Beck MJ. Temperature effects on desorption behavior and characteristic Wulff shapes of scandate cathodes. 2020 IEEE 21st International Conference on Vacuum Electronics (IVEC) 20-23 April 2020. Monterey: IEEE; 2020. p. 83-84. DOI:10.1109/ IVEC45766.2020.9520596</mixed-citation></citation-alternatives></ref><ref id="cit15"><label>15</label><citation-alternatives><mixed-citation xml:lang="ru">Kapustin VI, Li IP, Shumanov AV. Electronic structure of variants of scandate cathodes. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Moscow: Nanoindustry; 2021. p. 272-277.</mixed-citation><mixed-citation xml:lang="en">Kapustin VI, Li IP, Shumanov AV. Electronic structure of variants of scandate cathodes. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Moscow: Nanoindustry; 2021. p. 272-277.</mixed-citation></citation-alternatives></ref><ref id="cit16"><label>16</label><citation-alternatives><mixed-citation xml:lang="ru">Dai C, Saidi P, Topping M, Béland LK, et al. A mechanism for basal vacancy loop formation in zirconium. Scripta Materialia. 2019;172:72-76. DOI:10.1016/j.scriptamat.2019.07.006</mixed-citation><mixed-citation xml:lang="en">Dai C, Saidi P, Topping M, Béland LK, et al. A mechanism for basal vacancy loop formation in zirconium. Scripta Materialia. 2019;172:72-76. DOI:10.1016/j.scriptamat.2019.07.006</mixed-citation></citation-alternatives></ref><ref id="cit17"><label>17</label><citation-alternatives><mixed-citation xml:lang="ru">Bouwknegt A, Kooi AG van der. Calorimetric measurements of the emission properties of oxide cathodes in a low-pressure gas discharge. Journal of Physics D: Applied Physics. 1975;8(8):952-963. DOI:10.1088/0022-3727/8/8/009</mixed-citation><mixed-citation xml:lang="en">Bouwknegt A, Kooi AG van der. Calorimetric measurements of the emission properties of oxide cathodes in a low-pressure gas discharge. Journal of Physics D: Applied Physics. 1975;8(8):952-963. DOI:10.1088/0022-3727/8/8/009</mixed-citation></citation-alternatives></ref><ref id="cit18"><label>18</label><citation-alternatives><mixed-citation xml:lang="ru">Cherepnin NV. Sorption phenomena in vacuum technology. Moscow: Soviet radio; 1973. p. 383. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Cherepnin NV. Sorption phenomena in vacuum technology. Moscow: Soviet radio; 1973. p. 383. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit19"><label>19</label><citation-alternatives><mixed-citation xml:lang="ru">Cherepnin NV. The basics of cleaning, decontamination and pumping in vacuum technology. Moscow: Soviet radio; 1967. p. 408. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Cherepnin NV. The basics of cleaning, decontamination and pumping in vacuum technology. Moscow: Soviet radio; 1967. p. 408. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit20"><label>20</label><citation-alternatives><mixed-citation xml:lang="ru">Kazenas EK, Tsvetkov YuV. Thermodynamics of oxide evaporation. Moscow: URSS; 2008. p. 474. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Kazenas EK, Tsvetkov YuV. Thermodynamics of oxide evaporation. Moscow: URSS; 2008. p. 474. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit21"><label>21</label><citation-alternatives><mixed-citation xml:lang="ru">Chernyak EN, Zakurdaev IV, Shuppe GN, Yakovlev VK. Asymmetric change of the thermoemission current and surface structure in crystals of refractory metals during oriented transfer processes. Bulletin of the Academy of Sciences of the USSR. Physical Series. 1973. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Chernyak EN, Zakurdaev IV, Shuppe GN, Yakovlev VK. Asymmetric change of the thermoemission current and surface structure in crystals of refractory metals during oriented transfer processes. Bulletin of the Academy of Sciences of the USSR. Physical Series. 1973. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit22"><label>22</label><citation-alternatives><mixed-citation xml:lang="ru">Dyke WP, Charbonnier FM, Strayer RW, Floyd RL, et al. Electrical stability and life of the heated field emission cathode. Journal of Applied Physics. 1960;31(5):790-805. DOI:10.1063/1.1735700</mixed-citation><mixed-citation xml:lang="en">Dyke WP, Charbonnier FM, Strayer RW, Floyd RL, et al. Electrical stability and life of the heated field emission cathode. Journal of Applied Physics. 1960;31(5):790-805. DOI:10.1063/1.1735700</mixed-citation></citation-alternatives></ref><ref id="cit23"><label>23</label><citation-alternatives><mixed-citation xml:lang="ru">Kuchina IYu, Polushin NI, Zakharova ES, Li IP, et al. Experimental support of magnetron nickel oxide cathode fabrication process. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2015;18(4):285-290. DOI:10.17073/ 1609-3577-2015-4-285-290</mixed-citation><mixed-citation xml:lang="en">Kuchina IYu, Polushin NI, Zakharova ES, Li IP, et al. Experimental support of magnetron nickel oxide cathode fabrication process. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2015;18(4):285-290. DOI:10.17073/ 1609-3577-2015-4-285-290</mixed-citation></citation-alternatives></ref><ref id="cit24"><label>24</label><citation-alternatives><mixed-citation xml:lang="ru">Khanbekov IF, Li IP, Petrov VS, Mikhaylov VP, et al. Research of acoustically stimulated thermal desorption in electrovacuum microwave devices. IOP Conference Series: Materials Science and Engineering. 2018;387:012032. DOI:10.1088/1757-899X/387/1/012032</mixed-citation><mixed-citation xml:lang="en">Khanbekov IF, Li IP, Petrov VS, Mikhaylov VP, et al. Research of acoustically stimulated thermal desorption in electrovacuum microwave devices. IOP Conference Series: Materials Science and Engineering. 2018;387:012032. DOI:10.1088/1757-899X/387/1/012032</mixed-citation></citation-alternatives></ref><ref id="cit25"><label>25</label><citation-alternatives><mixed-citation xml:lang="ru">Khanbekov IF, Mikhailov VP. Research of the ultrasonic activation processes of diffusion and desorption in electrovacuum devices. Nanoindustriya. 2022;15(1):20- 27. DOI:10.22184/1993-8578.2022.15.1.20.27 (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Khanbekov IF, Mikhailov VP. Research of the ultrasonic activation processes of diffusion and desorption in electrovacuum devices. Nanoindustriya. 2022;15(1):20- 27. DOI:10.22184/1993-8578.2022.15.1.20.27 (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit26"><label>26</label><citation-alternatives><mixed-citation xml:lang="ru">Liu Y, Tian H, Han Y, Xu Z, et al. Temperature variation of a thermionic cathode during electron emission. Science in China Series E: Technological Sciences. 2008;51(9):1497-1501. DOI:10.1007/s11431-008-0161-2</mixed-citation><mixed-citation xml:lang="en">Liu Y, Tian H, Han Y, Xu Z, et al. Temperature variation of a thermionic cathode during electron emission. Science in China Series E: Technological Sciences. 2008;51(9):1497-1501. DOI:10.1007/s11431-008-0161-2</mixed-citation></citation-alternatives></ref><ref id="cit27"><label>27</label><citation-alternatives><mixed-citation xml:lang="ru">Hara T, Ishiguro T, Shinozaki K. Ultravioletlight-induced desorption of oxygen from SrTiO3 surfaces. Japanese Journal of Applied Physics. 2011;50(4R): 041502. DOI:10.1143/JJAP.50.041502</mixed-citation><mixed-citation xml:lang="en">Hara T, Ishiguro T, Shinozaki K. Ultravioletlight-induced desorption of oxygen from SrTiO3 surfaces. Japanese Journal of Applied Physics. 2011;50(4R): 041502. DOI:10.1143/JJAP.50.041502</mixed-citation></citation-alternatives></ref><ref id="cit28"><label>28</label><citation-alternatives><mixed-citation xml:lang="ru">Yates JT, Madey TE. Vibrational spectroscopy of molecules on surfaces. Boston: Springer US; 1987. p. 468.</mixed-citation><mixed-citation xml:lang="en">Yates JT, Madey TE. Vibrational spectroscopy of molecules on surfaces. Boston: Springer US; 1987. p. 468.</mixed-citation></citation-alternatives></ref><ref id="cit29"><label>29</label><citation-alternatives><mixed-citation xml:lang="ru">Kolacek K, Schmidt J, Straus J, Frolov O, et al. Interaction of extreme ultraviolet laser radiation with solid surface: ablation, desorption, nanostructuring. SPIE Proceedings XX International Symposium on High-Power Laser Systems and Applications 2014. China: SPIE; 2015. p. 92553U. DOI:10.1117/12.2071273</mixed-citation><mixed-citation xml:lang="en">Kolacek K, Schmidt J, Straus J, Frolov O, et al. Interaction of extreme ultraviolet laser radiation with solid surface: ablation, desorption, nanostructuring. SPIE Proceedings XX International Symposium on High-Power Laser Systems and Applications 2014. China: SPIE; 2015. p. 92553U. DOI:10.1117/12.2071273</mixed-citation></citation-alternatives></ref><ref id="cit30"><label>30</label><citation-alternatives><mixed-citation xml:lang="ru">Voronin VI, Lemyakin AA, Zorkina OA. Nest pumping of electrovacuum devices with ion-plasma electrode cleaning. Vestnik Saratovskogo gosudarstvennogo tekhnicheskogo universiteta. 2008;2(1(32)):119-126. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Voronin VI, Lemyakin AA, Zorkina OA. Nest pumping of electrovacuum devices with ion-plasma electrode cleaning. Vestnik Saratovskogo gosudarstvennogo tekhnicheskogo universiteta. 2008;2(1(32)):119-126. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit31"><label>31</label><citation-alternatives><mixed-citation xml:lang="ru">Lu S, Sun X, Zhang B, Wu J. Review of cathode plasma electrolysis treatment: progress, applications, and advancements in metal coating preparation. Materials. 2024;17(16):3929. DOI:10.3390/ma17163929</mixed-citation><mixed-citation xml:lang="en">Lu S, Sun X, Zhang B, Wu J. Review of cathode plasma electrolysis treatment: progress, applications, and advancements in metal coating preparation. Materials. 2024;17(16):3929. DOI:10.3390/ma17163929</mixed-citation></citation-alternatives></ref><ref id="cit32"><label>32</label><citation-alternatives><mixed-citation xml:lang="ru">Ramezani M, Mohd RZ, Pasang T, Jiang C-P. Surface engineering of metals: techniques, characterizations and applications. Metals. 2023;13(7): 1299. DOI:10.3390/met13071299</mixed-citation><mixed-citation xml:lang="en">Ramezani M, Mohd RZ, Pasang T, Jiang C-P. Surface engineering of metals: techniques, characterizations and applications. Metals. 2023;13(7): 1299. DOI:10.3390/met13071299</mixed-citation></citation-alternatives></ref><ref id="cit33"><label>33</label><citation-alternatives><mixed-citation xml:lang="ru">Pshyk AV, Petrov I, Bakhit B, Lu J, et al. Energyefficient physical vapor deposition of dense and hard Ti–Al–W–N coatings deposited under industrial conditions. Materials &amp; Design. 2023;227:111753. DOI:10.1016/j.matdes.2023.111753</mixed-citation><mixed-citation xml:lang="en">Pshyk AV, Petrov I, Bakhit B, Lu J, et al. Energyefficient physical vapor deposition of dense and hard Ti–Al–W–N coatings deposited under industrial conditions. Materials &amp; Design. 2023;227:111753. DOI:10.1016/j.matdes.2023.111753</mixed-citation></citation-alternatives></ref><ref id="cit34"><label>34</label><citation-alternatives><mixed-citation xml:lang="ru">Yang L, Zhang P, Shi J, Liang J, et al. Dual electrolytic plasma processing for steel surface cleaning and passivation. Journal of Materials Engineering and Performance. 2017;26(10):5009-5015. DOI:10.1007/ s11665-017-2826-0</mixed-citation><mixed-citation xml:lang="en">Yang L, Zhang P, Shi J, Liang J, et al. Dual electrolytic plasma processing for steel surface cleaning and passivation. Journal of Materials Engineering and Performance. 2017;26(10):5009-5015. DOI:10.1007/ s11665-017-2826-0</mixed-citation></citation-alternatives></ref><ref id="cit35"><label>35</label><citation-alternatives><mixed-citation xml:lang="ru">Zorkin AYa, Semenov AS, Konyushkov GV. Method of pumping electric vacuum devices. Russian Federation patent 2,185,676. 20 September 2021. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Zorkin AYa, Semenov AS, Konyushkov GV. Method of pumping electric vacuum devices. Russian Federation patent 2,185,676. 20 September 2021. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit36"><label>36</label><citation-alternatives><mixed-citation xml:lang="ru">Besozzi E, Maffini A, Dellasega D, Russo V, et al. Nanosecond laser pulses for mimicking thermal effects on nanostructured tungsten-based materials. Nuclear Fusion. 2018;58(3):036019. DOI:10.1088/1741-4326/aaa5d5</mixed-citation><mixed-citation xml:lang="en">Besozzi E, Maffini A, Dellasega D, Russo V, et al. Nanosecond laser pulses for mimicking thermal effects on nanostructured tungsten-based materials. Nuclear Fusion. 2018;58(3):036019. DOI:10.1088/1741-4326/aaa5d5</mixed-citation></citation-alternatives></ref><ref id="cit37"><label>37</label><citation-alternatives><mixed-citation xml:lang="ru">Lukin VG, Khvostenko OG. Desorption processes in the measurement of weak currents. Physics-Uspekhi. 2020;63(5):487-499. DOI:10.3367/UFNe.2019.07.038615</mixed-citation><mixed-citation xml:lang="en">Lukin VG, Khvostenko OG. Desorption processes in the measurement of weak currents. Physics-Uspekhi. 2020;63(5):487-499. DOI:10.3367/UFNe.2019.07.038615</mixed-citation></citation-alternatives></ref><ref id="cit38"><label>38</label><citation-alternatives><mixed-citation xml:lang="ru">Nikolaev AG, Oks EM, Frolova VP, Yushkov GYu, et al. Effect of the discharge parameters on the generation of deuterium ions in the plasma of a high-current pulsed vacuum arc with a composite zirconium deuteride cathode. Zhurnal tekhnicheskoy fiziki = Technical Physics. 2017; 87(5):681-687. DOI:10.21883/JTF.2017.05.44439.1912 (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Nikolaev AG, Oks EM, Frolova VP, Yushkov GYu, et al. Effect of the discharge parameters on the generation of deuterium ions in the plasma of a high-current pulsed vacuum arc with a composite zirconium deuteride cathode. Zhurnal tekhnicheskoy fiziki = Technical Physics. 2017; 87(5):681-687. DOI:10.21883/JTF.2017.05.44439.1912 (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit39"><label>39</label><citation-alternatives><mixed-citation xml:lang="ru">Santecchia E, Hamouda AMS, Musharavati F, Zalnezhad E, et al. Wear resistance investigation of titanium nitride-based coatings. Ceramics International. 2015;41(9):10349-10379. DOI:10.1016/j.ceramint.2015.04.152</mixed-citation><mixed-citation xml:lang="en">Santecchia E, Hamouda AMS, Musharavati F, Zalnezhad E, et al. Wear resistance investigation of titanium nitride-based coatings. Ceramics International. 2015;41(9):10349-10379. DOI:10.1016/j.ceramint.2015.04.152</mixed-citation></citation-alternatives></ref><ref id="cit40"><label>40</label><citation-alternatives><mixed-citation xml:lang="ru">Mustata I, Lungu C, Jepu I, Porosnicu C. Thermionic vacuum discharges for thin film depositions. Coatings. 2023;13(9):1500. DOI:10.3390/coatings13091500 41. Menzel D, Gomer R. Desorption from metal surfaces by low-energy electrons. The Journal of Chemical Physics. 1964;41(11):3311-3328. DOI:10.1063/1.1725730</mixed-citation><mixed-citation xml:lang="en">Mustata I, Lungu C, Jepu I, Porosnicu C. Thermionic vacuum discharges for thin film depositions. Coatings. 2023;13(9):1500. DOI:10.3390/coatings13091500 41. Menzel D, Gomer R. Desorption from metal surfaces by low-energy electrons. The Journal of Chemical Physics. 1964;41(11):3311-3328. DOI:10.1063/1.1725730</mixed-citation></citation-alternatives></ref><ref id="cit41"><label>41</label><citation-alternatives><mixed-citation xml:lang="ru">Li N, Li X, Zeng B. Field emission and emissionstimulated desorption of ZnO nanomaterials. Applied Sciences. 2018;8(3):382. DOI:10.3390/app8030382</mixed-citation><mixed-citation xml:lang="en">Li N, Li X, Zeng B. Field emission and emissionstimulated desorption of ZnO nanomaterials. Applied Sciences. 2018;8(3):382. DOI:10.3390/app8030382</mixed-citation></citation-alternatives></ref><ref id="cit42"><label>42</label><citation-alternatives><mixed-citation xml:lang="ru">Tyurin YuI, Nikitenkov NN, Larionov VV. Ionizing radiation-stimulated diffusion and desorption of hydrogen from metals. Russian Journal of Physical Chemistry A. 2011;85(6):1047-1053. DOI:10.1134/ S0036024411060318</mixed-citation><mixed-citation xml:lang="en">Tyurin YuI, Nikitenkov NN, Larionov VV. Ionizing radiation-stimulated diffusion and desorption of hydrogen from metals. Russian Journal of Physical Chemistry A. 2011;85(6):1047-1053. DOI:10.1134/ S0036024411060318</mixed-citation></citation-alternatives></ref><ref id="cit43"><label>43</label><citation-alternatives><mixed-citation xml:lang="ru">Dowell DH, King FK, Kirby RE, Schmerge JF, et al. In situ cleaning of metal cathodes using a hydrogen ion beam. Physical Review Special Topics – Accelerators and Beams. 2006;9(6):063502. DOI:10.1103/ PhysRevSTAB.9.063502</mixed-citation><mixed-citation xml:lang="en">Dowell DH, King FK, Kirby RE, Schmerge JF, et al. In situ cleaning of metal cathodes using a hydrogen ion beam. Physical Review Special Topics – Accelerators and Beams. 2006;9(6):063502. DOI:10.1103/ PhysRevSTAB.9.063502</mixed-citation></citation-alternatives></ref><ref id="cit44"><label>44</label><citation-alternatives><mixed-citation xml:lang="ru">Diamond WT. A model of gas desorption and radiation during initial high voltage conditioning in vacuum. Journal of Applied Physics. 2019;126(19):193303. DOI:10.1063/1.5124105</mixed-citation><mixed-citation xml:lang="en">Diamond WT. A model of gas desorption and radiation during initial high voltage conditioning in vacuum. Journal of Applied Physics. 2019;126(19):193303. DOI:10.1063/1.5124105</mixed-citation></citation-alternatives></ref><ref id="cit45"><label>45</label><citation-alternatives><mixed-citation xml:lang="ru">Yakunin AN, Aban’shin NP, Akchurin GG, Akchurin GG, et al. On the problems of stability and durability of field-emission current sources for electrovacuum devices. Proceedings SPIE 976, Ultrafast Phenomena and Nanophotonics XX. San Francisco: SPIE; 2016. p. 974620. DOI:10.1117/12.2213218</mixed-citation><mixed-citation xml:lang="en">Yakunin AN, Aban’shin NP, Akchurin GG, Akchurin GG, et al. On the problems of stability and durability of field-emission current sources for electrovacuum devices. Proceedings SPIE 976, Ultrafast Phenomena and Nanophotonics XX. San Francisco: SPIE; 2016. p. 974620. DOI:10.1117/12.2213218</mixed-citation></citation-alternatives></ref><ref id="cit46"><label>46</label><citation-alternatives><mixed-citation xml:lang="ru">Yafarov RK, Storublev AV. Stability of the emission characteristics of thermal and cold-field cathodes operating in a vacuum. Russian Microelectronics. 2021;50(2):102-107. DOI:10.1134/S1063739721020104</mixed-citation><mixed-citation xml:lang="en">Yafarov RK, Storublev AV. Stability of the emission characteristics of thermal and cold-field cathodes operating in a vacuum. Russian Microelectronics. 2021;50(2):102-107. DOI:10.1134/S1063739721020104</mixed-citation></citation-alternatives></ref><ref id="cit47"><label>47</label><citation-alternatives><mixed-citation xml:lang="ru">Semenov SV, Konyushkov GV, Zorkin AYa. Comprehensive research and analysis of the problems of palladium-barium metal alloy cathodes of high-power vacuum devices. Vakuumnaya tekhnika i tekhnologiya = Vacuum engineering and technology. 2012;45-52. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Semenov SV, Konyushkov GV, Zorkin AYa. Comprehensive research and analysis of the problems of palladium-barium metal alloy cathodes of high-power vacuum devices. Vakuumnaya tekhnika i tekhnologiya = Vacuum engineering and technology. 2012;45-52. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit48"><label>48</label><citation-alternatives><mixed-citation xml:lang="ru">Bhattacharya R, Turchetti M, Keithley PD, Berggren KK, Browning J. Long term stability study of planar, two-terminal field emitters. 2021 22nd International Vacuum Electronics Conference (IVEC). Rotterdam: IEEE; 2021. p. 1-2. DOI:10.1109/IVEC51707.2021.9722417</mixed-citation><mixed-citation xml:lang="en">Bhattacharya R, Turchetti M, Keithley PD, Berggren KK, Browning J. Long term stability study of planar, two-terminal field emitters. 2021 22nd International Vacuum Electronics Conference (IVEC). Rotterdam: IEEE; 2021. p. 1-2. DOI:10.1109/IVEC51707.2021.9722417</mixed-citation></citation-alternatives></ref><ref id="cit49"><label>49</label><citation-alternatives><mixed-citation xml:lang="ru">Khanbekov I, Petrov V, Kopytov D. Determination of vacuum properties of materials in the production of vacuum electronics devices. XXX Scientific and technical conference with the participation of foreign experts ‘Vacuum science and technology’ 2023, 10-14 October. Makhachkala: NOK “Zhuravli”; 2023. p. 49-50.</mixed-citation><mixed-citation xml:lang="en">Khanbekov I, Petrov V, Kopytov D. Determination of vacuum properties of materials in the production of vacuum electronics devices. XXX Scientific and technical conference with the participation of foreign experts ‘Vacuum science and technology’ 2023, 10-14 October. Makhachkala: NOK “Zhuravli”; 2023. p. 49-50.</mixed-citation></citation-alternatives></ref><ref id="cit50"><label>50</label><citation-alternatives><mixed-citation xml:lang="ru">Seif MN, Balk TJ, Beck MJ. Desorption from hot scandate cathodes: effects on vacuum device interior surfaces after long-term operation. Materials. 2020;13(22):5149. DOI:10.3390/ma13225149</mixed-citation><mixed-citation xml:lang="en">Seif MN, Balk TJ, Beck MJ. Desorption from hot scandate cathodes: effects on vacuum device interior surfaces after long-term operation. Materials. 2020;13(22):5149. DOI:10.3390/ma13225149</mixed-citation></citation-alternatives></ref><ref id="cit51"><label>51</label><citation-alternatives><mixed-citation xml:lang="ru">Pratton M. An introduction to surface physics. Izhevsk: SIC ‘Regular and chaotic dynamics’; 2000. p. 256. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Pratton M. An introduction to surface physics. Izhevsk: SIC ‘Regular and chaotic dynamics’; 2000. p. 256. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit52"><label>52</label><citation-alternatives><mixed-citation xml:lang="ru">Korzhavy AP, Zvonetsky VI, Mirzoeva SD, Shishkov AV, Alexandrova GN. Method of manufacturing a secondary emission cathode. Russian Federation patent 2,069,915. 25 July 2024. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Korzhavy AP, Zvonetsky VI, Mirzoeva SD, Shishkov AV, Alexandrova GN. Method of manufacturing a secondary emission cathode. Russian Federation patent 2,069,915. 25 July 2024. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit53"><label>53</label><citation-alternatives><mixed-citation xml:lang="ru">Ageev VN, Zandberg ÉY, Ionov NI, Tontegode AY. Adsorption-desorption processes on solid surfaces. Soviet Physics Uspekhi. 1983;26(4):382-383. DOI:10.1070/PU1983v026n04ABEH004394</mixed-citation><mixed-citation xml:lang="en">Ageev VN, Zandberg ÉY, Ionov NI, Tontegode AY. Adsorption-desorption processes on solid surfaces. Soviet Physics Uspekhi. 1983;26(4):382-383. DOI:10.1070/PU1983v026n04ABEH004394</mixed-citation></citation-alternatives></ref><ref id="cit54"><label>54</label><citation-alternatives><mixed-citation xml:lang="ru">Zubenko YuV, Ishmukhamedov MB. The effect of germanium on the adsorption bond of barium with tungsten. Fizika tverdogo tela = Physics of the Solid State. 1983;25(1):180-183. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Zubenko YuV, Ishmukhamedov MB. The effect of germanium on the adsorption bond of barium with tungsten. Fizika tverdogo tela = Physics of the Solid State. 1983;25(1):180-183. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit55"><label>55</label><citation-alternatives><mixed-citation xml:lang="ru">Kapustin VI, Li IP, Shumanov AV, Lebedinskii YuYu, et al. Physical operating principles of scandate cathodes for microwave devices. Technical Physics. 2017;62(1):116-126. DOI:10.1134/S1063784217010108</mixed-citation><mixed-citation xml:lang="en">Kapustin VI, Li IP, Shumanov AV, Lebedinskii YuYu, et al. Physical operating principles of scandate cathodes for microwave devices. Technical Physics. 2017;62(1):116-126. DOI:10.1134/S1063784217010108</mixed-citation></citation-alternatives></ref><ref id="cit56"><label>56</label><citation-alternatives><mixed-citation xml:lang="ru">Santecchia E, Hamouda AMS, Musharavati F, Zalnezhad E, et al. Wear resistance investigation of titanium nitride-based coatings. Ceramics International. 2015;41(9):10349-10379. DOI:10.1016/j.ceramint.2015.04.152</mixed-citation><mixed-citation xml:lang="en">Santecchia E, Hamouda AMS, Musharavati F, Zalnezhad E, et al. Wear resistance investigation of titanium nitride-based coatings. Ceramics International. 2015;41(9):10349-10379. DOI:10.1016/j.ceramint.2015.04.152</mixed-citation></citation-alternatives></ref><ref id="cit57"><label>57</label><citation-alternatives><mixed-citation xml:lang="ru">Niemelä J-P, Marin G, Karppinen M. Titanium dioxide thin films by atomic layer deposition: a review. Semiconductor Science and Technology. 2017;32(9): 093005. DOI:10.1088/1361-6641/aa78ce</mixed-citation><mixed-citation xml:lang="en">Niemelä J-P, Marin G, Karppinen M. Titanium dioxide thin films by atomic layer deposition: a review. Semiconductor Science and Technology. 2017;32(9): 093005. DOI:10.1088/1361-6641/aa78ce</mixed-citation></citation-alternatives></ref><ref id="cit58"><label>58</label><citation-alternatives><mixed-citation xml:lang="ru">Rakhadilov BK, Miniyazov AZh, Skakov MK, Sagdoldina ZhB, et al. Structural modification and erosion of plasma-irradiated tungsten and molybdenum surfaces. Technical Physics. 2020;65(3):382-391. DOI:10.1134/S1063784220030202</mixed-citation><mixed-citation xml:lang="en">Rakhadilov BK, Miniyazov AZh, Skakov MK, Sagdoldina ZhB, et al. Structural modification and erosion of plasma-irradiated tungsten and molybdenum surfaces. Technical Physics. 2020;65(3):382-391. DOI:10.1134/S1063784220030202</mixed-citation></citation-alternatives></ref><ref id="cit59"><label>59</label><citation-alternatives><mixed-citation xml:lang="ru">Lee W-J, Hon M-H. Space-limited crystal growth mechanism of TiO2 films by atomic layer deposition. The Journal of Physical Chemistry C. 2010;114(15):6917- 6921. DOI:10.1021/jp911210q</mixed-citation><mixed-citation xml:lang="en">Lee W-J, Hon M-H. Space-limited crystal growth mechanism of TiO2 films by atomic layer deposition. The Journal of Physical Chemistry C. 2010;114(15):6917- 6921. DOI:10.1021/jp911210q</mixed-citation></citation-alternatives></ref><ref id="cit60"><label>60</label><citation-alternatives><mixed-citation xml:lang="ru">Wang F-Z, Zhang H, Ding B-J, Zhu R-H. A thermionic tungsten cathode activated with nanothoria and prepared by swaging method. Materials Science and Engineering: A. 2002;336(1-2):59-63. DOI:10.1016/S0921-5093(01)01969-4</mixed-citation><mixed-citation xml:lang="en">Wang F-Z, Zhang H, Ding B-J, Zhu R-H. A thermionic tungsten cathode activated with nanothoria and prepared by swaging method. Materials Science and Engineering: A. 2002;336(1-2):59-63. DOI:10.1016/S0921-5093(01)01969-4</mixed-citation></citation-alternatives></ref><ref id="cit61"><label>61</label><citation-alternatives><mixed-citation xml:lang="ru">Chao-Long L, Xin Z, Jiu-Xing Z, Fan-Xing Z, et al. Preparation and property of La1–xNdxB6 cathode material. Journal of Inorganic Materials. 2015;30(4):363. DOI:10.15541/jim20140471</mixed-citation><mixed-citation xml:lang="en">Chao-Long L, Xin Z, Jiu-Xing Z, Fan-Xing Z, et al. Preparation and property of La1–xNdxB6 cathode material. Journal of Inorganic Materials. 2015;30(4):363. DOI:10.15541/jim20140471</mixed-citation></citation-alternatives></ref><ref id="cit62"><label>62</label><citation-alternatives><mixed-citation xml:lang="ru">Chang S-C, Hung S-C, Lin T-C, Yu T-A, et al. Thermal stability of hydrogen annealed aluminum doped zinc oxide films investigated by thermal desorption spectroscopy. 2013 8th International Microsystems, Packaging, Assembly and Circuits Technology Conference (IMPACT). Taipei: IEEE; 2013. p. 279-282. DOI:10.1109/IMPACT.2013.6706639</mixed-citation><mixed-citation xml:lang="en">Chang S-C, Hung S-C, Lin T-C, Yu T-A, et al. Thermal stability of hydrogen annealed aluminum doped zinc oxide films investigated by thermal desorption spectroscopy. 2013 8th International Microsystems, Packaging, Assembly and Circuits Technology Conference (IMPACT). Taipei: IEEE; 2013. p. 279-282. DOI:10.1109/IMPACT.2013.6706639</mixed-citation></citation-alternatives></ref><ref id="cit63"><label>63</label><citation-alternatives><mixed-citation xml:lang="ru">Li I. Nanostructures in palladium-barium cathodes of microwave devices. Electronics: Science, Technology, Business. 2018;(5):144-151. DOI:10.22184/1992-4178.2018.176.5.144.151</mixed-citation><mixed-citation xml:lang="en">Li I. Nanostructures in palladium-barium cathodes of microwave devices. Electronics: Science, Technology, Business. 2018;(5):144-151. DOI:10.22184/1992-4178.2018.176.5.144.151</mixed-citation></citation-alternatives></ref><ref id="cit64"><label>64</label><citation-alternatives><mixed-citation xml:lang="ru">Kapustin VI. Physicochemical foundations of creation of the multicomponent oxide-containing cathode materials. Perspektivnye materialy = Inorganic Materials: Applied Research. 2000;(2):5-17. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Kapustin VI. Physicochemical foundations of creation of the multicomponent oxide-containing cathode materials. Perspektivnye materialy = Inorganic Materials: Applied Research. 2000;(2):5-17. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit65"><label>65</label><citation-alternatives><mixed-citation xml:lang="ru">Kapustin VI, Li IP, Petrov VS, Ledentsova NE, Turbina AV. Electronic structure and physical-chemical peculiarities of nickel oxide cathode materials. Elektronnaya Tekhnika. Seriya 1: SVCH-Tekhnika. 2016; 1(528):8-18. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Kapustin VI, Li IP, Petrov VS, Ledentsova NE, Turbina AV. Electronic structure and physical-chemical peculiarities of nickel oxide cathode materials. Elektronnaya Tekhnika. Seriya 1: SVCH-Tekhnika. 2016; 1(528):8-18. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit66"><label>66</label><citation-alternatives><mixed-citation xml:lang="ru">Kapustin VI, Li IP, Kozhevnikova NE. Trace impurities have synergistic effects on electronic structure of oxide-nickel cathodes. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Sudak: Nanoindustry; 2021. p. 267-271. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Kapustin VI, Li IP, Kozhevnikova NE. Trace impurities have synergistic effects on electronic structure of oxide-nickel cathodes. XXVIII Scientific and Technical Conference with the participation of foreign specialists "Vacuum science and technology". Sudak: Nanoindustry; 2021. p. 267-271. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit67"><label>67</label><citation-alternatives><mixed-citation xml:lang="ru">Norman D, Tuck RA, Skinner HB, Wadsworth PJ, et al. Surface structure of thermionic-emission cathodes. Physical Review Letters. 1987;58(5):519-522. DOI:10.1103/PhysRevLett.58.519</mixed-citation><mixed-citation xml:lang="en">Norman D, Tuck RA, Skinner HB, Wadsworth PJ, et al. Surface structure of thermionic-emission cathodes. Physical Review Letters. 1987;58(5):519-522. DOI:10.1103/PhysRevLett.58.519</mixed-citation></citation-alternatives></ref><ref id="cit68"><label>68</label><citation-alternatives><mixed-citation xml:lang="ru">Djubua BCh, Koultashev OK, Polivnikova OV. Emission electronics, nanotechnology, synergetics (to the history of ideas in cathode technology). Elektronnaya tekhnika. Seriya 1: SVCH-Tekhnika. 2008;4(497):3-22. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Djubua BCh, Koultashev OK, Polivnikova OV. Emission electronics, nanotechnology, synergetics (to the history of ideas in cathode technology). Elektronnaya tekhnika. Seriya 1: SVCH-Tekhnika. 2008;4(497):3-22. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit69"><label>69</label><citation-alternatives><mixed-citation xml:lang="ru">Thomas RE, Morrill CD. Secondary emission properties of impregnated tungsten cathodes. Applications of Surface Science. 1983;16(1-2):292-311. DOI:10.1016/ 0378-5963(83)90075-2</mixed-citation><mixed-citation xml:lang="en">Thomas RE, Morrill CD. Secondary emission properties of impregnated tungsten cathodes. Applications of Surface Science. 1983;16(1-2):292-311. DOI:10.1016/ 0378-5963(83)90075-2</mixed-citation></citation-alternatives></ref><ref id="cit70"><label>70</label><citation-alternatives><mixed-citation xml:lang="ru">Kapustin VI, Li IP, Moskalenko SO, Shumanov AV. Theory of thermionic and secondary emission properties of palladium–barium cathodes of microwave electrovacuum devices. Technical Physics. 2020;65(2):317-323. DOI:10.1134/S1063784220020073</mixed-citation><mixed-citation xml:lang="en">Kapustin VI, Li IP, Moskalenko SO, Shumanov AV. Theory of thermionic and secondary emission properties of palladium–barium cathodes of microwave electrovacuum devices. Technical Physics. 2020;65(2):317-323. DOI:10.1134/S1063784220020073</mixed-citation></citation-alternatives></ref><ref id="cit71"><label>71</label><citation-alternatives><mixed-citation xml:lang="ru">Pashkov AN, Romanova YuV, Popov RN, Dubinina OV, Khabachev MN. The development of production technology for cathode alloys based on platinum group metals for high-power electrovacuum microwave devices. Elektronnaya Tekhnika. Seriya 1: SVCH-Tekhnika. 2014;4(523):73-77. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Pashkov AN, Romanova YuV, Popov RN, Dubinina OV, Khabachev MN. The development of production technology for cathode alloys based on platinum group metals for high-power electrovacuum microwave devices. Elektronnaya Tekhnika. Seriya 1: SVCH-Tekhnika. 2014;4(523):73-77. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit72"><label>72</label><citation-alternatives><mixed-citation xml:lang="ru">Gaidar AI, Bondarenko GG, Petrov VS, Kashirina NV. Surface processes at the first stage of magnetron cathode Pd–Pd5Ba activation. Vacuum. 2018;154:333-339. DOI:10.1016/j.vacuum.2018.05.024</mixed-citation><mixed-citation xml:lang="en">Gaidar AI, Bondarenko GG, Petrov VS, Kashirina NV. Surface processes at the first stage of magnetron cathode Pd–Pd5Ba activation. Vacuum. 2018;154:333-339. DOI:10.1016/j.vacuum.2018.05.024</mixed-citation></citation-alternatives></ref><ref id="cit73"><label>73</label><citation-alternatives><mixed-citation xml:lang="ru">Kostishyn VG, Kaloshkin SD, Adantsov AYu, Ursulyak ND, et al. Stusy of the phase and impurity composition of Pd–Ba and Pt–Ba cathode alloys. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2015;18(3):212-220. DOI:10.17073/1609-3577-2015-3- 212-220 (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Kostishyn VG, Kaloshkin SD, Adantsov AYu, Ursulyak ND, et al. Stusy of the phase and impurity composition of Pd–Ba and Pt–Ba cathode alloys. Izvestiya Vysshikh Uchebnykh Zavedenii. Materialy Elektronnoi Tekhniki = Materials of Electronics Engineering. 2015;18(3):212-220. DOI:10.17073/1609-3577-2015-3- 212-220 (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit74"><label>74</label><citation-alternatives><mixed-citation xml:lang="ru">Zorkin AYa, Myasnikova S. Technology of manufacturing metal-alloy cathodes for millimeter-wave magnetrons. Materials of the XVI scientific and technical conference "Vacuum science and Technology". Moscow: MIEM; 2009. p. 210-212. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Zorkin AYa, Myasnikova S. Technology of manufacturing metal-alloy cathodes for millimeter-wave magnetrons. Materials of the XVI scientific and technical conference "Vacuum science and Technology". Moscow: MIEM; 2009. p. 210-212. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit75"><label>75</label><citation-alternatives><mixed-citation xml:lang="ru">Khabachev MN, Makarov AP, Drovnenkova GV, Zhukov YuA, et al. The industrial technology for the production of barium cathode alloys based on platinum and palladium for high-power microwave devices. Elektronnaya Tekhnika. Seriya 1: SVCH-Tekhnika. 2021;(4(551)):49-66. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Khabachev MN, Makarov AP, Drovnenkova GV, Zhukov YuA, et al. The industrial technology for the production of barium cathode alloys based on platinum and palladium for high-power microwave devices. Elektronnaya Tekhnika. Seriya 1: SVCH-Tekhnika. 2021;(4(551)):49-66. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit76"><label>76</label><citation-alternatives><mixed-citation xml:lang="ru">Li IP, Petrov VS, Polyakov VS, Silaev AD, et al. Simultaneous activation of the autoelectronic and secondary emission cathode of the magnetron with initial start. Izvestiya vysshikh uchebnykh zavedeniy. Elektronika = Semiconductors. 2014;3(107):30-37. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Li IP, Petrov VS, Polyakov VS, Silaev AD, et al. Simultaneous activation of the autoelectronic and secondary emission cathode of the magnetron with initial start. Izvestiya vysshikh uchebnykh zavedeniy. Elektronika = Semiconductors. 2014;3(107):30-37. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit77"><label>77</label><citation-alternatives><mixed-citation xml:lang="ru">Li IP, Komissarchik SV, Lifanov ND. Magnetron with initial start with special activation of autoelectronic cathodes. Russian Federation patent 2,494,489. 27 September 2013. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Li IP, Komissarchik SV, Lifanov ND. Magnetron with initial start with special activation of autoelectronic cathodes. Russian Federation patent 2,494,489. 27 September 2013. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit78"><label>78</label><citation-alternatives><mixed-citation xml:lang="ru">Alekseev YuV, Kanicheva IR. Comparison of the emission properties and auger spectrum of an alloy emitter. Bulletin of the Academy of Sciences of the USSR. Physical Series. 1976;40:2587-2590. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Alekseev YuV, Kanicheva IR. Comparison of the emission properties and auger spectrum of an alloy emitter. Bulletin of the Academy of Sciences of the USSR. Physical Series. 1976;40:2587-2590. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit79"><label>79</label><citation-alternatives><mixed-citation xml:lang="ru">Sytnik AYa, Overcooked CH. The change in the emission properties of a cathode based on a palladiumbarium alloy under the influence of ion bombardment under gas discharge conditions. Elektronnaya Tekhnika. Seriya 1: SVCH-Tekhnika. 1977;(12):98-102. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Sytnik AYa, Overcooked CH. The change in the emission properties of a cathode based on a palladiumbarium alloy under the influence of ion bombardment under gas discharge conditions. Elektronnaya Tekhnika. Seriya 1: SVCH-Tekhnika. 1977;(12):98-102. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit80"><label>80</label><citation-alternatives><mixed-citation xml:lang="ru">Li IP, Bondarenko GG. The use of hydrogenvacuum treatment of palladium powders to obtain effective metal-alloy cathodes of a steel magnetron. Perspektivnyye materialy = Inorganic Materials: Applied Research. 2012;(1);30-34. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Li IP, Bondarenko GG. The use of hydrogenvacuum treatment of palladium powders to obtain effective metal-alloy cathodes of a steel magnetron. Perspektivnyye materialy = Inorganic Materials: Applied Research. 2012;(1);30-34. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit81"><label>81</label><citation-alternatives><mixed-citation xml:lang="ru">Swanwick ME, Keathley PD, Kartner FX, Velasquez-Garcia LF. Ultrafast photo-triggered field emission cathodes using massive, uniform arrays of nanosharp high-aspect-ratio silicon structures. 2013 Transducers &amp; Eurosensors XXVII: The 17th International Conference on Solid-State Sensors, Actuators and Microsystems (Transducers &amp; Eurosensors XXVII). Barcelona: IEEE; 2013. p. 2680-2683. DOI:10.1109/Transducers.2013.6627358</mixed-citation><mixed-citation xml:lang="en">Swanwick ME, Keathley PD, Kartner FX, Velasquez-Garcia LF. Ultrafast photo-triggered field emission cathodes using massive, uniform arrays of nanosharp high-aspect-ratio silicon structures. 2013 Transducers &amp; Eurosensors XXVII: The 17th International Conference on Solid-State Sensors, Actuators and Microsystems (Transducers &amp; Eurosensors XXVII). Barcelona: IEEE; 2013. p. 2680-2683. DOI:10.1109/Transducers.2013.6627358</mixed-citation></citation-alternatives></ref><ref id="cit82"><label>82</label><citation-alternatives><mixed-citation xml:lang="ru">Nechaev YS, Denisov EA, Cheretaeva AO, Shurygina NA, et al. Method of thermal desorption study of hydrogen states in carbon materials and nanomaterials. Physics-Uspekhi. 2023;66(09):936-942. DOI:10.3367/UFNe.2022.11.039274</mixed-citation><mixed-citation xml:lang="en">Nechaev YS, Denisov EA, Cheretaeva AO, Shurygina NA, et al. Method of thermal desorption study of hydrogen states in carbon materials and nanomaterials. Physics-Uspekhi. 2023;66(09):936-942. DOI:10.3367/UFNe.2022.11.039274</mixed-citation></citation-alternatives></ref><ref id="cit83"><label>83</label><citation-alternatives><mixed-citation xml:lang="ru">Rochanachirapar W, Murakami K, Yamasaki N, Abo S, et al. Influence of gas atmosphere during laser surface treatment of CNT cathode. Technical Digest of the 17th International Vacuum Nanoelectronics Conference (IEEE Cat. No.04TH8737). Cambridge: IEEE; 2004. p. 144-145. DOI:10.1109/IVNC.2004.1354941</mixed-citation><mixed-citation xml:lang="en">Rochanachirapar W, Murakami K, Yamasaki N, Abo S, et al. Influence of gas atmosphere during laser surface treatment of CNT cathode. Technical Digest of the 17th International Vacuum Nanoelectronics Conference (IEEE Cat. No.04TH8737). Cambridge: IEEE; 2004. p. 144-145. DOI:10.1109/IVNC.2004.1354941</mixed-citation></citation-alternatives></ref><ref id="cit84"><label>84</label><citation-alternatives><mixed-citation xml:lang="ru">Arkhipov AV, Gabdullin PG, Gnuchev NM, Davydov SN, et al. Field-induced electron emission from nanoporous carbon of various types. St. Petersburg Polytechnical University Journal: Physics and Mathematics. 2015;1(1):47-55. DOI:10.1016/j.spjpm.2015.03.011</mixed-citation><mixed-citation xml:lang="en">Arkhipov AV, Gabdullin PG, Gnuchev NM, Davydov SN, et al. Field-induced electron emission from nanoporous carbon of various types. St. Petersburg Polytechnical University Journal: Physics and Mathematics. 2015;1(1):47-55. DOI:10.1016/j.spjpm.2015.03.011</mixed-citation></citation-alternatives></ref><ref id="cit85"><label>85</label><citation-alternatives><mixed-citation xml:lang="ru">Fursey GN, Polyakov MA, Kantonistov A, Yafyasova M, et al. Autoelectronic and explosive emission from graphene-like structures. Zhurnal tekhnicheskoy fiziki = Technical Physics. 2013;83(6):71-77. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Fursey GN, Polyakov MA, Kantonistov A, Yafyasova M, et al. Autoelectronic and explosive emission from graphene-like structures. Zhurnal tekhnicheskoy fiziki = Technical Physics. 2013;83(6):71-77. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit86"><label>86</label><citation-alternatives><mixed-citation xml:lang="ru">Bernatsky DP, Pavlov V. Field electron microscopy of carbonized rhenium. Pis′ma v zhurnal tekhnicheskoy fiziki = Technical Physics Letters. 2017; 43(12):104. DOI:10.21883/PJTF.2017.12.44715.16748. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Bernatsky DP, Pavlov V. Field electron microscopy of carbonized rhenium. Pis′ma v zhurnal tekhnicheskoy fiziki = Technical Physics Letters. 2017; 43(12):104. DOI:10.21883/PJTF.2017.12.44715.16748. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit87"><label>87</label><citation-alternatives><mixed-citation xml:lang="ru">Krachkovskaya TM, Storublev AV, Sahaji GV, Yemelyanov AS. Investigation of the characteristics of a metal-porous cathode modified with nanocarbon. Collection of articles VII of the All-Russian Conference. ”Microwave Electronics and Microelectronics". St. Petersburg: St. Petersburg State Technical University ”LETI“; 2018. p. 155-159. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Krachkovskaya TM, Storublev AV, Sahaji GV, Yemelyanov AS. Investigation of the characteristics of a metal-porous cathode modified with nanocarbon. Collection of articles VII of the All-Russian Conference. ”Microwave Electronics and Microelectronics". St. Petersburg: St. Petersburg State Technical University ”LETI“; 2018. p. 155-159. (In Russ.)</mixed-citation></citation-alternatives></ref><ref id="cit88"><label>88</label><citation-alternatives><mixed-citation xml:lang="ru">Krachkovskaya TM, Melnikov LA. Emission properties of metal-porous cathodes modified with nanocarbon. Pis′ma v zhurnal tekhnicheskoy fiziki = Technical Physics Letters. 2018;44(22):11-18. (In Russ.)</mixed-citation><mixed-citation xml:lang="en">Krachkovskaya TM, Melnikov LA. Emission properties of metal-porous cathodes modified with nanocarbon. Pis′ma v zhurnal tekhnicheskoy fiziki = Technical Physics Letters. 2018;44(22):11-18. (In Russ.)</mixed-citation></citation-alternatives></ref></ref-list><fn-group><fn fn-type="conflict"><p>The authors declare that there are no conflicts of interest present.</p></fn></fn-group></back></article>
